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Mort is an early one but the series really gets into the swing of things once all the main characters have been introduced and a history established. There are lots of in-jokes and each story gets more substantial as you move along the timeline. However, that being said, the books do fall into broad categories and one fan has created a suggested reading order for newbies, if you're interested. http://www.lspace.org/books/reading-order-guides/the-discworld-reading-order-guide-1-5.jpg
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